반응 #75018

ord-918feb052ddd4aa081fbb6b976105ed8

반응 방정식

CCC(=O)[O-].[K+]
potassium propionate
C=Cc1ccccc1
Styrene
CC1CC(c2ccccc2)OC1=O
alpha-methyl-gamma-phenyl butyrolactone
수율 50.0%

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    workup.WAITIn less than an hour

실험 절차

Styrene in an amount of 2.1 grams and 11.65 grams of manganic acetate, Mn(C2H3O2)3.2H2O, comprising two equivalents of Mn+3 based on titration value, were refluxed under nitrogen in 200 milliliters of propionic acid containing 20 grams of potassium propionate. In less than an hour, a 50% yield of alpha-methyl-gamma-phenyl butyrolactone was obtained.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04175089uspto-grants-1979_11