반응 #74968

반응 방정식

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione

→

crystals

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4-dihydro-1,4-methanonaphthalene-5,8-diol

용매

methanol

반응 조건

후처리

1. 1
   workup.DISSOLUTIONwere dissolved in 50 ml
2. 2
   온도the solution was refluxed strongly for three hours
3. 3
   기타Evaporation of the methanol
4. 4
   기타yielded an oily material which
5. 5
   기타upon recrystallization twice from Skelly B

실험 절차

10 g. of 6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione, prepared according to Example 8, were dissolved in 50 ml. of methanol. A few drops of pyridine were added and the solution was refluxed strongly for three hours. Evaporation of the methanol yielded an oily material which upon recrystallization twice from Skelly B gave white needle crystals melting at 96° C.-98° C.

출처