반응 #74963

반응 방정식

Hexachlorocyclopentadiene

tert-butyl-p-benzoquinone

→

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

용매

toluene

반응 조건

후처리

1. 1
   세척The solid was washed with methanol
2. 2
   기타recrystallized from benzene
3. 3
   기타Yellow crystals were obtained melting at 124°-125° C.

실험 절차

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

출처