반응 #742244

ord-4bada835d65a4d73ba88e933bd63e29b

반응 방정식

CCOC(=O)CC=P(c1ccccc1)(c1ccccc1)c1ccccc1
(carbethoxyethylidene)triphenyl phosphorane
O=Cc1ccccc1O
salicylaldehyde
CCOC(=O)/C(C)=C/c1ccccc1O
(E)-3-(2-Hydroxy-phenyl)-2-methyl-acrylic acid ethyl ester

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도while cooling in an ice-bath
  2. 2
    세척washed

실험 절차

To a solution of 75.0 g (carbethoxyethylidene)triphenyl phosphorane in 350 ml of toluene, 23.2 g of salicylaldehyde was dropped in at 20° C. while cooling in an ice-bath. After stirring at room temperature for 90 mn., the reaction mixture was diluted with toluene and washed to neutrality with water.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: USRE043006E1uspto-grants-2011_12