반응 #73695

반응 방정식

maleic anhydride

p-toluenesulfonic acid

diethanolamine

iodine

→

diphenylmethane diisocyanate

용매

diethylene glycol

반응 조건

후처리

1. 1
   workup.STIRRINGThe mixture was stirred for 23 hours at a temperature between about 210° F. and about 226° F
2. 2
   workup.STIRRINGwith stirring
3. 3
   workup.STIRRINGThe mixture was stirred under vacuum for 8 hours at a temperature between about 210° F. and about 230° F.
4. 4
   기타to give a liquid soybean oil

실험 절차

The above amounts of diethanolamine and iodine were added to the above amount of soybean oil with stirring. The mixture was stirred for 23 hours at a temperature between about 210° F. and about 226° F. Then, the above amounts of maleic anhydride, diethylene glycol, and p-toluenesulfonic acid were added with stirring. The mixture was stirred under vacuum for 8 hours at a temperature between about 210° F. and about 230° F. to give a liquid soybean oil based polyol with a hydroxyl number of 55. A reaction mixture of about 10.00 grams of the polyol and the above indicated amount of diphenylmethane diisocyanate yielded a solid soybean oil based polyurethane material.

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