반응 #73692

반응 방정식

maleic anhydride

sulfuric acid

toluene

diethanolamine

iodine

→

diphenylmethane diisocyanate

반응 조건

후처리

1. 1
   workup.STIRRINGThe mixture was stirred for 22 hours at a temperature between about 180° F. and about 225° F
2. 2
   workup.STIRRINGwith stirring
3. 3
   온도The mixture was refluxed for 8 hours
4. 4
   workup.DISTILLATIONdistilling trap
5. 5
   workup.DISTILLATIONdistilled out of solvent
6. 6
   기타to give a liquid soybean oil

실험 절차

The above amounts of diethanolamine and iodine were added to the above amount of soybean oil with stirring. The mixture was stirred for 22 hours at a temperature between about 180° F. and about 225° F. Then, the above amounts of maleic anhydride, toluene and sulfuric acid were added with stirring. The mixture was refluxed for 8 hours using a Dean-Stark distilling trap, then distilled out of solvent to give a liquid soybean oil based polyol with a hydroxyl number of 53. A reaction mixture of about 10.00 grams of the polyol and the above indicated amount of diphenylmethane diisocyanate yielded a solid soybean oil based polyurethane material.

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