반응 #71573

반응 방정식

tetrahydrothiopyran-4-one

methyltrifluoromethane sulfonate

→

Methyl-Tetrahydrothiopyran-4-One Triflate

용매

dichloromethane

반응 조건

후처리

1. 1
   기타The solvent was removed after about 30 minutes
2. 2
   기타was then recrystallized with a mixture of ethyl acetate and hexane (1:2 by weight)
3. 3
   기타to obtain a white solid product
4. 4
   여과The solid product was filtered
5. 5
   기타dried for 1 hour in an oven at 50° C.
6. 6
   기타to obtain the following product

실험 절차

2 mmol of tetrahydrothiopyran-4-one was dissolved in 5 ml of dichloromethane at 0° C., and about 2 mmol of methyltrifluoromethane sulfonate was slowly dripped to the mixture. The solvent was removed after about 30 minutes, and was then recrystallized with a mixture of ethyl acetate and hexane (1:2 by weight) to obtain a white solid product. The solid product was filtered and dried for 1 hour in an oven at 50° C. to obtain the following product:

출처