반응 #71320

반응 방정식

V-601

V-601

phenoxyethyl acrylate

methyl methacrylate

acrylic acid

V-601

→

phenoxyethyl acrylate methyl methacrylate acrylic acid

용매

isopropanol

methyl ethyl ketone

methyl ethyl ketone

methyl ethyl ketone

반응 조건

후처리

1. 1
   기타equipped with a stirrer
2. 2
   온도Thereafter, while the temperature inside the flask was maintained at 75° C.
3. 3
   workup.ADDITIONAfter the dropwise addition
4. 4
   workup.STIRRINGthe contents of the flask were stirred at 75° C. for 2 hours
5. 5
   온도Then, the temperature inside the flask was increased to 85° C.
6. 6
   workup.STIRRINGstirring
7. 7
   workup.WAITwas continued for another 2 hours

실험 절차

360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained.

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