반응 #712188

ord-abd7e8ad4bfd46fcaa945a1958fe69bf

반응 방정식

CC(C)(C)OC(=O)N1CC2(CC2)CC1C(=O)O
5-(tert-butoxycarbonyl)-5-azaspiro[2.4]heptane-6-carboxylic acid
N
ammonia
CC(C)(C)OC(=O)N1CC2(CC2)CC1C(N)=O
title compound
수율 78.0%
CC(C)(C)OC(=O)N1CC2(CC2)CC1C(N)=O
tert-Butyl 6-carbamoyl-5-azaspiro[2.4]heptane-5-carboxylate
수율 78.0%

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

In analogy to the procedure described in Example 127 c), 5-(tert-butoxycarbonyl)-5-azaspiro[2.4]heptane-6-carboxylic acid (CAN 1454843-77-6, 112 mg, 464 μmol) was condensed with ammonia to give the title compound (87 mg, 78%) as colorless liquid, MS (EI): m/e=240.0 [M+].

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US09303012B2uspto-grants-2016_04