반응 #710516

반응 방정식

diethylamine

triethylammonium

diethyl dithiocarbamate

carbon disulfide

triethylamine

→

final product

triethylammonium N,N-diethyl dithiocarbamate

반응 조건

후처리

1. 1
   온도maintain the temperature below 30° C
2. 2
   기타to remove the excess amine
3. 3
   기타for the removal of low volatiles

실험 절차

Preparation of triethylammonium salt of diethyl dithiocarbamate is as follows: 76 grams (1 mole) carbon disulfide and 101 grams (1 mole) triethylamine are mixed at 10° C. under nitrogen. To the mixture is added in slowly 80.5 grams (1.1 mole) diethylamine drop wise and maintain the temperature below 30° C. Then the mixture is heated to 50° C. for 1 hour. The solution is then stripped out under vacuum to remove the excess amine and for the removal of low volatiles to obtain final product. The acid number (normally below 30) is measured to check the acidity. The product purity (ranging between 85-95%) is measured by LC-MS and NMR.

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