반응 #71011

반응 방정식

4-hydroxybutylacrylate glycidylether

2-benzoyl benzoic acid

acetonitrile

2,6-di-tert-butyl-4-methylphenol

→

2-benzoyl-benzoic acid 3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

용매

dimethylacetamide

반응 조건

후처리

1. 1
   온도was heated to reflux
2. 2
   온도at reflux temperature for 16 hours

실험 절차

A reaction mixture containing 2-benzoyl benzoic acid (40.0 g, 0.1722 mol), acetonitrile (300 mL), dimethylacetamide (10 mL), tetrabutylammonium bromide (5.6 g, 17.22 mmol) and 2,6-di-tert-butyl-4-methylphenol (0.3 g, 1.4 mmol) was heated to reflux. At this temperature 4-hydroxybutylacrylate glycidylether (28.0 g, 140 mmol) was added and the mixture was allowed to stir at reflux temperature for 16 hours.

출처