반응 #696695

반응 방정식

1,4-diaminobutane

triethylamine

2-chloro-2-methyl-3-nitrosopentane

→

2-(4-aminobutyl)amino-2-methyl-3-pentanone oxime

용매

acetonitrile

acetonitrile

반응 조건

후처리

1. 1
   기타to precipitate
2. 2
   workup.STIRRINGThe reaction mixture was stirred overnight
3. 3
   여과the product was filtered off
4. 4
   기타dried in vacuo
5. 5
   기타to give a white powder, (0.5 g; 86%)

실험 절차

To a stirred solution of 1,4-diaminobutane (0.26 g; 2.9 mmol) and triethylamine (0.33 g; 3.2 mmol) in acetonitrile (5 ml) was added a solution of 2-chloro-2-methyl-3-nitrosopentane (0.485 g; 3.24 mmol) in acetonitrile (5 ml). After stirring for ca 10 minutes the product began to precipitate. The reaction mixture was stirred overnight and the product was filtered off and dried in vacuo to give a white powder, (0.5 g; 86%).

출처