반응 #67718

ord-98b5a59ed8fd4b229550e2884de4185c

반응 방정식

CC(=O)O
acetic acid
O=C1OC(=O)c2ccccc21
phthalic anhydride
Cc1ccccc1C
o-xylene
O=C(O)c1ccccc1C(=O)O
phthalic acid
O=C1OC(=O)c2ccccc21
phthalic anhydride

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

As an example, reference is made to the production of phthalic anhydride with acetic acid as solvent. During oxidation of o-xylene as feedstock, phthalic acid and phthalic anhydride are obtained as products in the liquid-phase reactor. Therefore, not only the binary crystallization curves of phthalic acid in acetic acid or phthalic anhydride in acetic acid are used, but also those of the ternary system phthalic acid/phthalic anhydride/in acetic acid. By using the process of the invention, phthalic acid and phthalic anhydride are obtained as pure solid products. The acetic acid obtained as byproduct is recirculated into the reactor as solvent.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08524922B2uspto-grants-2013_09