반응 #674284

반응 방정식

4-butoxybenzene-1,3-diamine dihydrochloride

2-[ethyl(4-nitrosophenyl)amino]ethanol

→

2-{[4-(2-amino-5-ethoxy-4-imino cyclohexa-2,5-dienylideneamino)phenyl]-ethylamino}ethanol hydrochloride

용매

sodium hydroxide

water

반응 조건

후처리

1. 1
   기타the supernatant is removed
2. 2
   세척the residual gum is washed with water
3. 3
   기타The solid formed
4. 4
   여과is filtered off
5. 5
   기타dried

실험 절차

A solution of 4-butoxybenzene-1,3-diamine dihydrochloride in 4.2 ml of 0.25N sodium hydroxide is added to a solution of 2-[ethyl(4-nitrosophenyl)amino]ethanol in 4.2 ml of water at 50° C. After 3 hours at 50° C., the supernatant is removed and the residual gum is washed with water and then taken up in isopropyl ether. The solid formed is filtered off and dried. 360 mg of 2-{[4-(2-amino-5-ethoxy-4-imino cyclohexa-2,5-dienylideneamino)phenyl]-ethylamino}ethanol hydrochloride 65 are thus obtained in the form of a black powder.

출처