반응 #674283

반응 방정식

hydrogen peroxide

N-ethyl-N-isopropyl-4-aminoaniline hydrochloride

4-butoxybenzene-1,3-diamine dihydrochloride

ethanol

ammonia

→

2-[[4-(2-amino-5-butoxy-4-iminocyclohexa-2,5-dienylideneamino)phenyl](2-hydroxyethyl)amino]ethanol

용매

water

반응 조건

후처리

1. 1
   기타the ethanol is removed
2. 2
   기타the coupling product formed
3. 3
   추출is extracted with butanol
4. 4
   기타After removal of the butanol under vacuum

실험 절차

To a solution of 0.925 g (0.003 mol) of N-ethyl-N-isopropyl-4-aminoaniline hydrochloride and 0.76 g (0.003 mol) of 4-butoxybenzene-1,3-diamine dihydrochloride in 2 ml of water and 6 ml of ethanol, brought to pH 9.5 with 20% aqueous ammonia, are added 10.2 ml of 6% aqueous hydrogen peroxide solution. After stirring for 24 hours at room temperature, the ethanol is removed and the coupling product formed is extracted with butanol. After removal of the butanol under vacuum, the gummy residue is taken up in ethyl acetate and then in ether. 0.470 g of 2-[[4-(2-amino-5-butoxy-4-iminocyclohexa-2,5-dienylideneamino)phenyl](2-hydroxyethyl)amino]ethanol 10 is obtained in the form of a blue-black powder after drying.

출처