반응 #67266

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5-bromo-2-[(2S)-oxiran-2-ylmethoxy]benzaldehyde

m-CPBA

→

5-BROMO-2-[(2S)-OXIRAN-2-YLMETHOXY]PHENYL FORMATE

용매

DCM

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후처리

1. 1
   기타Preparation
2. 2
   온도The mixture was heated
3. 3
   온도at reflux for 3 h

실험 절차

Preparation according to Preparation 2 using 5-bromo-2-[(2S)-oxiran-2-ylmethoxy]benzaldehyde (8.3 g, 32 mmol), DCM (100 ml) and m-CPBA (77%, 10.9 g, 48.6 mmol). The mixture was heated at reflux for 3 h. Crude yield: 8.5 g. MS m/z (rel. intensity, 70 eV) 274 (M+, 10), 273 (M+, 9), 189 (98), 188 (bp), 57 (77).

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