반응 #6669

반응 방정식

sodium carbonate

CH3CHClCOOH

CH2═CHCH2CH2OH

sulfuric acid

→

CH3CHClCOOCH2CH2CH═CH2

용매

t-butylmethyl ether

t-butylmethyl ether

water

반응 조건

후처리

1. 1
   세척The organic layer was washed with 150 ml of water
2. 2
   건조dried over magnesium sulfate
3. 3
   여과subjected to filtration
4. 4
   기타to obtain a crude liquid
5. 5
   농축The crude liquid was concentrated

실험 절차

CH3CHClCOOH (50 g) and CH2═CHCH2CH2OH (75 ml) were put into a flask, and 10 ml of concentrated sulfuric acid was added dropwise, followed by stirring at room temperature for 10 minutes. The reaction solution was poured into 250 ml of a saturated sodium carbonate aqueous solution. 150 ml of water and 150 ml of t-butylmethyl ether were added for liquid separation to obtain a t-butylmethyl ether layer as an organic layer. The organic layer was washed with 150 ml of water, dried over magnesium sulfate and then subjected to filtration to obtain a crude liquid. The crude liquid was concentrated to obtain CH3CHClCOOCH2CH2CH═CH2.

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