반응 #65879

반응 방정식

vinyldimethylchlorosilane

allyldichlorosilane

→

7-methyl-4,4,7-trichloro-4,7-disila-1-octene

수율 89.0%

용매

isopropanol

반응 조건

후처리

1. 1
   workup.ADDITIONwere added to the flask
2. 2
   기타the solution was further reacted for 2 hrs
3. 3
   기타the reaction
4. 4
   workup.DISTILLATIONVacuum distillation (48°-52° C./0.5 torr) of the product mixture

실험 절차

Using the same apparatus and procedure described in EXAMPLE 1, 25.3 g (0.21 mol) of vinyldimethylchlorosilane and 50 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mol) of allyldichlorosilane for 30 rain at 80° C. and the solution was further reacted for 2 hrs to complete the reaction. Vacuum distillation (48°-52° C./0.5 torr) of the product mixture gave 16.2 g (89%) of 7-methyl-4,4,7-trichloro-4,7-disila-1-octene.

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