반응 #65279

반응 방정식

methyl 2,3-dichloro-4-methylbenzoate

N-bromosuccinimide

carbon tetrachloride

→

material

수율 99.0%

methyl 4-bromomethyl-2,3-dichlorobenzoate

수율 99.0%

용매

pentane

반응 조건

후처리

1. 1
   기타while being irradiated with a 150 watt flood lamp for 2.5 hours
2. 2
   기타Concentration of the filtered reaction mixture under vacuum

실험 절차

A mixture of 40 g (0.183 mol) of methyl 2,3-dichloro-4-methylbenzoate, 34.17 g (0.192 mol) of N-bromosuccinimide, 0.4 g (0.0017 mol) of benzoylperoxide, and 640 mL of carbon tetrachloride was stirred at room temperature while being irradiated with a 150 watt flood lamp for 2.5 hours. Concentration of the filtered reaction mixture under vacuum gave 54 g of material which on trituration with pentane followed by storage of the slurry at 5° C. for 18 hours gave 34.6 g (63.5%) of product; mp 57°-61° C.

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