반응 #6503

반응 방정식

ethoxalyl chloride

p-hydroxyethylstyrene

triethylamine

→

aimed compound

p-ethoxalyloxyethylstyrene

용매

benzene

반응 조건

후처리

1. 1
   기타A 200 ml flask equipped with a stirrer
2. 2
   workup.ADDITIONTo the mixture was added dropwise
3. 3
   기타to precipitate a hydrochloride of triethylamine (white solid)
4. 4
   workup.ADDITION80 g of hexane was added to complete precipitation of the hydrochloride
5. 5
   기타The hydrochloride is removed by filteration
6. 6
   기타condensed

실험 절차

A 200 ml flask equipped with a stirrer, a thermometer and a dropping funnel was charged with 14.8 g (0.1 mol) of p-hydroxyethylstyrene, 150 ml of benzene and 10.1 g (0.1 mol) of triethylamine and cooled to 10° C. To the mixture was added dropwise with stirring 13.7 g (0.1 mol) of ethoxalyl chloride for one hour at 10° C. to precipitate a hydrochloride of triethylamine (white solid). After mixting at room temperature for 2 hours, 80 g of hexane was added to complete precipitation of the hydrochloride. The hydrochloride is removed by filteration and the resultant filtrate was condensed to obtain the aimed compound. The compound was identified by 1H NMR (360 Mz) and IR. ##STR7##

출처