반응 #64245

ord-b24ebc5c9e1b4814845e2e28f2770630

반응 방정식

CN(C=O)[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-N-formyl-4-nitroxycyclohexylamine
CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-4-nitroxycyclohexylamine
→
O=CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-formyl-4-nitroxycyclohexylamine
수율 60.0%

반응물

CN(C=O)[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-N-formyl-4-nitroxycyclohexylamine
CN[C@H]1CC[C@H](O[N+](=O)[O-])CC1
trans-N-methyl-4-nitroxycyclohexylamine

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

trans-N-methyl-N-formyl-4-nitroxycyclohexylamine from trans-N-methyl-4-nitroxycyclohexylamine melting point: 52°-54° C. (ether/isohexane), yield: 60% of theory.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05411989uspto-grants-1995_05