반응 #64235

ord-95f61b892d9b4419a2ca820c0f9db754

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    추출extracted with ether
  2. 2
    건조The ether solution was dried
  3. 3
    기타evaporated
  4. 4
    기타The residue was purified by chromatography

실험 절차

To a suspension of 7.4 g of 60% sodium hydride in 100 ml of dimethylformamide was added a solution of 8-hydroxy-7-methoxy-1-octene in 150 ml of dimethylformamide over 1.5 hours. A 63.4 g portion of the tosylate of 1-hexadecanol was added and the mixture was stirred for 18 hours, poured into water and extracted with ether. The ether solution was dried and evaporated. The residue was purified by chromatography giving 41.5 g of the title compound as a oil.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05411983uspto-grants-1995_05