반응 #640568

ord-357c4cbcd5cd4528851205250f3de92c

반응 방정식

CCOCC
diethyl ether
O=C(CBr)c1ccccc1
Phenacyl bromide
C1CCSC1
tetrahydrothiophene
O
water
O=C(C[S+]1CCCC1)c1ccccc1.[Br-]
Phenacyltetrahydrothiophenium Bromide

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타The aqueous layer separated

실험 절차

Phenacyl bromide, 88.2 g (0.44 mole) and tetrahydrothiophene, 39.1 g (0.44 mole) were dissolved in 220 g of nitromethane, which was stirred for 4 hours at room temperature. The reaction solution was combined with 800 g of water and 400 g of diethyl ether. The aqueous layer separated was taken out, which was an aqueous solution of the target compound, phenacyltetrahydrothiophenium bromide.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08048610B2uspto-grants-2011_11