반응 #640548

반응 방정식

2-trimethylsilyloxy-1,3-cyclohexadiene

methyl tetrolate

→

methyl 2-methyl-4-trimethylsilyloxybenzoate

수율 67.1%

용매

toluene

반응 조건

후처리

1. 1
   기타A 50 mL round bottom flask equipped with magnetic stir bar and condenser
2. 2
   농축The raction was concentrated in vacuo

실험 절차

A 50 mL round bottom flask equipped with magnetic stir bar and condenser was charged with 6.0 g of 2-trimethylsilyloxy-1,3-cyclohexadiene, 3.5 g methyl tetrolate in 3 mL dry toluene. The reaction was heated to 150° C. for 50 hours at which point 1H-NMR indicated no starting diene. The raction was concentrated in vacuo to provide 5.7 g (67%) methyl 2-methyl-4-trimethylsilyloxybenzoate.

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