반응 #6384
ord-97f55f6466014133b0ecc5caef9de86e
반응 방정식
4-chlorophenyl 4-chlorobenzyl sulfide
4-chlorobenzyl alcohol
hydrogen tetrafluoroborate
→
4-chlorophenylbis(4-chlorobenzyl)sulfonium tetrafluoroborate
수율 77.4%
반응 조건
상세 조건
See reaction.notes.procedure_details.
실험 절차
5.2 g (19.4 mmol) of 4-chlorophenyl 4-chlorobenzyl sulfide, 4.14 g (29.0 mmol) of 4-chlorobenzyl alcohol and 14.15 g (87 mmol) of hydrogen tetrafluoroborate (54% in diethyl ether) in 20 ml of methylene chloride are reacted as in Example 6a) to give 7.23 g (77.4% of theory) of 4-chlorophenylbis(4-chlorobenzyl)sulfonium tetrafluoroborate in the form of white-beige crystals of melting point 147°-148° C.