반응 #63356

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1-(4-nitrophenyl)-3-azabicyclo[3.1.1]heptane-2,4-dione

→

title compound

1-(4-aminophenyl)-3-azabicyclo[3.1.1]heptane-2,4-dione

용매

2-methoxyethanol

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실험 절차

In a manner analogous to that described in Example 1a, 5.0 g of 1-(4-nitrophenyl)-3-azabicyclo[3.1.1]heptane-2,4-dione in 250 ml of 2-methoxyethanol are hydrogenated at 45° in the presence of 0.5 g of 5% palladium-on-carbon and worked up. The title compound is obtained which, after recrystallisation from 2-methoxyethanol, melts at 265° with decomposition.

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