반응 #63270

ord-67ea4b0a1462429cbc7a0a109d6d2d88

반응 방정식

c1ccc2[nH]ccc2c1
indole
C=CC(=O)O
acrylic acid
O=C(O)CCc1c[nH]c2ccccc12
indole-3-propionic acid

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

Reaction of indole XXI with acrylic acid in the presence of acetic acid affords the indole-3-propionic acid. Esterification, alkylation of the indole nitrogen, if desired, and trifluoroacetic acid hydrolysis gives rise to indoles of Formula VII in which R is (CH2)mCO2R9, m is 2 and R2 is H or C1 -C3 alkyl. ##STR29##

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04764610uspto-grants-1988_08