반응 #631977

반응 방정식

potassium chloride

divinyldichlorosilane

potassium tert-butoxide

→

divinyl di-tert-butoxysilane

수율 56.5%

용매

hexane

hexane

반응 조건

후처리

1. 1
   기타equipped with a dropping funnel and a mechanical stirrer in a stream of nitrogen, and reaction
2. 2
   기타was removed by filtration
3. 3
   workup.DISTILLATIONthe obtained filtrate was distilled under reduced pressure

실험 절차

306 g (2.00 mol) of divinyldichlorosilane, 539 g (4.80 mol) of potassium tert-butoxide and 3.0 L of dry hexane were charged in a 5 L four-necked flask equipped with a dropping funnel and a mechanical stirrer in a stream of nitrogen, and reaction was carried out for 17 hours under reflux with hexane. After completion of the reaction, potassium chloride residue as a by-product was removed by filtration, and the obtained filtrate was distilled under reduced pressure to obtain 257 g (1.13 mol) of divinyl di-tert-butoxysilane as an aimed product. The yield was 56.5%.

출처