반응 #631975

ord-55cefff41d0346b1bd2437b3200c3d54

반응 방정식

O=C(Oc1ccc2cc(O)ccc2c1)c1ccccc1
6-hydroxy-2-naphthyl benzoate
O=[N+]([O-])O
nitric acid
O
water
O=C(Oc1ccc2c([N+](=O)[O-])c(O)ccc2c1)c1ccccc1
6-hydroxy-5-nitro-2-naphthyl benzoate

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타at 15° C.
  2. 2
    기타The thus obtained deposit was recrystallized from ethanol/acetic acid

실험 절차

The thus obtained 6-hydroxy-2-naphthyl benzoate was dispersed in acetic acid, nitric acid was added dropwise to the dispersion while keeping it at 15° C., and water was further added thereto, followed by stirring. The thus obtained deposit was recrystallized from ethanol/acetic acid to obtain 6-hydroxy-5-nitro-2-naphthyl benzoate.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07935395B2uspto-grants-2011_05