반응 #61886

ord-7d1005021b344960abba0f2bfa216f2f

반응 방정식

C=CC(=C)C
isoprene
C=CC=O
acrolein
CC1=CCC(CO)CC1
4-methyl-3-cyclohexenylmethanol

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타According to the well known Diels-Alder Reaction
  2. 2
    기타was synthesized

실험 절차

According to the well known Diels-Alder Reaction, using isoprene and acrolein as raw materials, 4-methyl-3-cyclohexenyl aldehyde was synthesized. The reaction was conducted under the conditions described in the literary documents of J. Amer, Chem. Soc., 119, 15, 1997, 3507-3512; and Tetrahedron Lett., 40, 32, 1999, 5817-5822. Subsequently, the compound was reduced to obtain 4-methyl-3-cyclohexenylmethanol at a high yield.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07429622B2uspto-grants-2008_09