반응 #613841

반응 방정식

Palmitoleic acid

Oleic acid

1-Octene

Palmitoleic acid

Methyl 9-Decenoate

ethene

→

Ethyl 9-Decenoate

1-Decene

반응 조건

후처리

1. 1
   기타a cross-metathesis reaction
2. 2
   기타to yield

실험 절차

Ethenolysis comprises a cross-metathesis reaction involving ethene. According to some preferred embodiments of the invention, a mixture of ethyl esters of Palmitoleic acid (C16:1) and Oleic acid (C18:1) are subjected to conditions of ethenolysis to yield a mixture of α-olefins (1-Octene and 1-Decene) and Methyl 9-Decenoate. See FIG. 8. The 1-Octene is a product unique to ethenolysis of Palmitoleic acid (C16:1). In the inventive method, Ethyl 9-Decenoate and 1-Decene will also form from the mixture of Palmitoleic and Oleic acid ethyl esters. Prior art methods using Oleic acid esters (Methyl Oleate) as the starting material only produce Methyl 9-Decenoate and 1-Decene.

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