반응 #6119

ord-68057794265042cf843f66f80857944b

반응 방정식

N#Cc1cc(C#N)c(Br)c(C#N)c1
2-bromo-3,5-dicyanobenzonitrile
C[S-].[Na+]
sodium thiomethylate
N#Cc1cc(C#N)c(S)c(C#N)c1
expected product
N#Cc1cc(C#N)c(S)c(C#N)c1
3,5-dicyano-2-mercaptobenzonitrile

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타If the procedure described in Preparation LV

실험 절차

If the procedure described in Preparation LV is followed starting from 6 g (26.10-3 mol) of 2-bromo-3,5-dicyanobenzonitrile and 6 g (86.10-3 mol) of sodium thiomethylate, 6 g (quantitative yield) of the expected product are obtained in the form of an oil.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05246961uspto-grants-1993_09