반응 #608265

ord-47086fea0aa24b8d8c6857cd612a9563

반응 방정식

Nc1cc(C(=O)O)ccc1F
3-amino-4-fluoro-benzoic acid
c1ccc2c(c1)CC[C@@H]1NCCC[C@H]21
cis-1,2,3,4,4a,5,6,10b-octahydro-benzo[f]quinoline
CN(C)C(On1nnc2cccnc21)=[N+](C)C.F[P-](F)(F)(F)(F)F
2-(7-aza-1H-benzotriazol-1-yl)-1,1,3,3-tetramethyluronium hexa-fluorophosphate
Nc1cc(C(=O)N2CCC[C@@H]3c4ccccc4CC[C@@H]32)ccc1F
title compound
수율 47.0%
Nc1cc(C(=O)N2CCC[C@@H]3c4ccccc4CC[C@@H]32)ccc1F
(3-Amino-4-fluoro-phenyl)-(cis-2,3,4a,5,6,10b-hexahydro-1H-benzo[f]quinolin-4-yl)-methanone
수율 47.0%

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The title compound is prepared from 3-amino-4-fluoro-benzoic acid and cis-1,2,3,4,4a,5,6,10b-octahydro-benzo[f]quinoline following a procedure analogous to that described in Example 1 [2-(7-aza-1H-benzotriazol-1-yl)-1,1,3,3-tetramethyluronium hexa-fluorophosphate is used]. Yield: 47% of theory; LC (method 4): tR=1.94 min; Mass spectrum (ESI+): m/z=325 [M+H]+.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US09328072B2uspto-grants-2016_05