반응 #60810

ord-bfa91bba01444c858e262522dcf3c6d5

반응 방정식

C[S-].[Na+]
sodium thiomethoxide
Cc1cc2ncnc(Cl)c2s1
6-methyl-4-chlorothieno[3,2-d]pyrimidine
CSc1ncnc2cc(C)sc12
title compound
수율 97.0%
CSc1ncnc2cc(C)sc12
6-Methyl-4-(methylthio)thieno[3,2-d]pyrimidine
수율 97.0%

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    여과The mixture was filtered
  2. 2
    세척the solid was washed with acetonitrile
  3. 3
    기타The combined filtrate and washes were evaporated

실험 절차

A solution of sodium thiomethoxide (24S mg) and 6-methyl-4-chlorothieno[3,2-d]pyrimidine (Acta Pol. Pharm. (1986), 43(2), 97-100) (650 mg) in acetonitrile (50 mL) was stirred overnight. The mixture was filtered and the solid was washed with acetonitrile. The combined filtrate and washes were evaporated to give the title compound as a white solid (665 mg, 97%);

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07427616B2uspto-grants-2008_09