반응 #6041

ord-7032a768e4ff40098e40773662a0af2f

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도is refluxed under nitrogen for 9 hours
  2. 2
    온도After cooling the mixture
  3. 3
    추출extracted with AcOEt
  4. 4
    기타evaporated to dryness

실험 절차

A mixture of 1-(4-fluorophenyl)hydrazine hydrochloride (1.03 g), ethyl 4-oxo-hexanoate (1.0 g), 2-propanol (25 ml) and H2SO4 is refluxed under nitrogen for 9 hours. After cooling the mixture is poured into a aqueous solution of NaHCO3, extracted with AcOEt and evaporated to dryness to yield 1.45 g of isopropyl 5-fluoro-3-methyl-1H-indole-2-propanoate.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05246957uspto-grants-1993_09