반응 #56369

반응 방정식

tris(2-chloroethyl)phosphate

dimethyl methylphosphonate

methylchloride

ethylene oxide

→

Tris(2-chloroethyl)Phosphate Dimethyl Methylphosphonate

용매

methanol

반응 조건

후처리

1. 1
   workup.ADDITIONA mixture of 571 g
2. 2
   기타26 hours
3. 3
   온도The product was then heated at 95° with 28.2 g

실험 절차

A mixture of 571 g. of tris(2-chloroethyl)phosphate and 531 g. of dimethyl methylphosphonate was heated at 181°-197° C. until 287.5 of methylchloride was evolved; this required 26 hours. The product was then heated at 95° with 28.2 g. of methanol, and finally treated with ethylene oxide at 90°-100° until substantially neutral. The product was useful as a flame retardant at 5-10 phr. in a styrenated polyester.

출처