반응 #56002

반응 방정식

potassium hydroxide

2,6-dimethylphenol chloroform ethanol

2,2-bis(4-acetoxyphenyl)propane

isophthalic acid

tetrachloroethane phenol

→

2,2-Bis(4-Hydroxyphenyl)Propane

반응 조건

후처리

1. 1
   온도under gradually increasing vacuum
2. 2
   기타to remove the acetic acid which
3. 3
   기타crystallized
4. 4
   기타The crystallized polymer is subjected to solid state polymerization under vacuum at 280° C. until the inherent viscosity
5. 5
   기타is then extruded at 350° C.

실험 절차

An equimolar mixture of 2,2-bis(4-acetoxyphenyl)propane (Bisphenol A diacetate) and isophthalic acid is heated gradualy to 290° C. in a stirred vessel under gradually increasing vacuum to remove the acetic acid which is liberated. When the melt viscosity of the condensate reaches a level such that stirring becomes difficult the melt is drained from the reaction vessel and crystallized. The crystallized polymer is subjected to solid state polymerization under vacuum at 280° C. until the inherent viscosity reaches 0.65 dl/g (in 40/60 by weight tetrachloroethane/phenol solution at 25° C.). The polymer is then extruded at 350° C. and pelletized. The polymer has an inherent viscosity of 0.62 and a carboxylic acid content of 40 microequivalents per gram (μeq./g), determined by potentiometric titration of a solution of the polymer in a 2,6-dimethylphenol/chloroform/ethanol mixture with an ethanolic solution of potassium hydroxide.

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