반응 #558756

반응 방정식

water

2,6-dinitrobenzonitrile

K2CO3

PhSH

→

title product

2-nitro-6-(phenylthio)benzonitrile

용매

DMF

반응 조건

후처리

1. 1
   workup.ADDITIONAfter the completion of addition
2. 2
   기타the resultant precipitation
3. 3
   여과was collected by filtration
4. 4
   세척washed with water
5. 5
   기타dried in the air

실험 절차

To a mixture of 2,6-dinitrobenzonitrile (2.0 g, 10.36 mmol) and K2CO3 (1.43 g, 10.36 mmol) in 5 mL of anhydrous DMF was added PhSH (1.14 ml in 5 mL of DMF) dropwise under nitrogen at 0° C. After the completion of addition, the reaction mixture was stirred at 0° C. for 0.5 hr. Then the reaction mixture was poured into 50 mL of water, the resultant precipitation was collected by filtration, washed with water and dried in the air to give the title product.

출처