반응 #55673

ord-5e686666afb648aaaad97f3640882fb7

반응 방정식

CC(=O)[O-]
acetate
CCCCCCCC(C)(C)Cl
dimethyloctyl chloride
C=CC(=C)CCC=C(C)C.Cl
myrcene hydrochloride
[Na+].[OH-]
sodium hydroxide
CC(=O)[O-].[Na+]
sodium acetate
CC(C)=CCC/C(C)=C/CO.CC(C)=CCC/C(C)=C\CO
nerol geraniol

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The dimethyloctyl chloride is then obtained by reacting the myrcene hydrochloride (neryl/geranyl chloride) with sodium acetate and saponifying the acetate with sodium hydroxide to produce nerol/geraniol. This is then hydrogenated to produce dimethyloctanol, which is treated with HCl in the presence of zinc chloride to produce the dimethyloctyl chloride.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04221742uspto-grants-1980_09