반응 #54883

반응 방정식

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxy-2-pentyne

hydrogen

→

title compound

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxypentane

용매

ethyl acetate

반응 조건

후처리

1. 1
   기타/in2 and 25° C
2. 2
   기타the catalyst is removed by filtration
3. 3
   기타the solvent is evaporated under vacuum

실험 절차

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxy-2-pentyne (10.8 g., 0.04 mole) is dissolved in ethyl acetate (100 ml.). 5% Palladium on carbon is added and the mixture is hydrogenated on the Parr apparatus at an initial pressure of 41 lbs./in2 and 25° C. When 0.08 mole of hydrogen is absorbed, the catalyst is removed by filtration and the solvent is evaporated under vacuum to give the title compound as a light orange residual oil.

출처