반응 #548706

반응 방정식

polyethylene

acetone cyclohexylhydrazone

oxygen

→

2-Cyclohexylazo-2-Hydroperoxypropane

수율 85.0%

용매

heptane

반응 조건

후처리

1. 1
   기타was initiated at 35° C
2. 2
   온도The solution was cooled to 0°
3. 3
   온도cooled
4. 4
   기타stored at -30° C

실험 절차

A solution of 5.0 grams (0.0324 moles) of acetone cyclohexylhydrazone in 70 grams of heptane was oxidized by passing oxygen through the solution as in Example II. The oxidation was initiated at 35° C. The reaction was followed by gas chromatography, following the disappearance of the cyclohexylhydrazone peak. The reaction was complete in 35 minutes at 35° C. The solution was cooled to 0° and drained into a tared, cooled, polyethylene bottle, weighed and stored at -30° C. The solution weighed 75.1 grams (85% yield).

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