반응 #54422

ord-c15b2d655b974c42b97f93dfd33e9347

반응 방정식

O=[N+]([O-])C=Cc1cc([N+](=O)[O-])ccc1Cl
2-chloro-β,5-dinitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate
→
CN(C)C(=S)SC(C[N+](=O)[O-])c1cc([N+](=O)[O-])ccc1Cl
2-chloro-5-nitro-α-(nitromethyl)benzyl dimethyldithiocarbamate

반응물

O=[N+]([O-])C=Cc1cc([N+](=O)[O-])ccc1Cl
2-chloro-β,5-dinitrostyrene
CN(C)C(=S)[S-].C[NH2+]C
dimethylammonium dimethyldithiocarbamate

시약

없음

용매

S=C=S
carbon disulfide

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

As in Example 17, reaction of 2-chloro-β,5-dinitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 2-chloro-5-nitro-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 120° C.-121° C. after recrystallization without heating from acetone-methanol solution.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04148795uspto-grants-1979_04