반응 #540661

ord-b7e106236f67431b89d04799599efada

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타at 50 to 60° C.
  2. 2
    기타this was further polymerized for 1 hour
  3. 3
    workup.WAITtaking 30 minutes
  4. 4
    기타this was further polymerized for 1 hour

실험 절차

Further subsequently, with temperature controlled so as to keep the system at 50 to 60° C., 2.88 kg of isoprene was continuously added to the reactor, taking 1 hour. After the addition of styrene, this was further polymerized for 1 hour. The polymerization conversion of isoprene was 100%. After this, 1.99 kg of styrene was continuously added to the reactor, taking 30 minutes. After the addition of styrene, this was further polymerized for 1 hour thereby giving two types of styrene/isoprene/styrene block copolymers with one of the respective two styrene blocks having a different molecular weight from each other. The polymerization conversion of styrene was 100%.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08492480B2uspto-grants-2013_07