반응 #53242

반응 방정식

Tetrahydrothiophene

phenacyl bromide

→

phenacyltetrahydrothiophenium bromide

수율 94.9%

용매

acetonitrile

acetonitrile

반응 조건

후처리

1. 1
   workup.ADDITIONwas slowly added a solution
2. 2
   기타obtained
3. 3
   기타a powder was precipitated
4. 4
   workup.ADDITIONThe reaction solution was poured into 1,500 ml of ethyl acetate
5. 5
   여과the powder was filtered out
6. 6
   기타dried

실험 절차

Tetrahydrothiophene (53.2 g) was dissolved in 400 ml of acetonitrile, and thereto was slowly added a solution obtained by dissolving 100 g of phenacyl bromide in 300 ml of acetonitrile, and the solution was stirred at room temperature for 3 hours, thereby a powder was precipitated. The reaction solution was poured into 1,500 ml of ethyl acetate, and the powder was filtered out and dried, thus 137 g of phenacyltetrahydrothiophenium bromide was obtained.

출처