반응 #53146

ord-811de8a4c783459ea43daad158495844

반응 방정식

Cl.NCc1ccc(N/C(=C2\C(=O)Nc3ccc([N+](=O)[O-])cc32)c2ccccc2)cc1
(Z)-3-[1-(4-aminomethyl-phenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone-hydrochloride
CCCC=O
butyraldehyde
[BH3-]C#N.[Na+]
sodium cyanoborohydride
→
CCCCN(CCCC)Cc1ccc(N/C(=C2\C(=O)Nc3ccc([N+](=O)[O-])cc32)c2ccccc2)cc1
(Z)-3-[1-(4-Dibutylaminomethyl-phenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone

반응물

Cl.NCc1ccc(N/C(=C2\C(=O)Nc3ccc([N+](=O)[O-])cc32)c2ccccc2)cc1
(Z)-3-[1-(4-aminomethyl-phenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone-hydrochloride
CCCC=O
butyraldehyde
[BH3-]C#N.[Na+]
sodium cyanoborohydride

시약

없음

용매

CO
methanol

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

Prepared analogously to Example 159 from (Z)-3-[1-(4-aminomethyl-phenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone-hydrochloride, butyraldehyde and sodium cyanoborohydride in methanol.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06855710B2uspto-grants-2005_02