반응 #52111

ord-0e763f365a82438db6bb844e525df0ba

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도an attached reflux condenser

실험 절차

2 mmol of N-hydroxyphthalimide and 4 mmol of di-tert-butyl peroxide are added at a temperature of 130° C. to 200 mmol of cyclooctane in a round-bottomed flask having an attached reflux condenser. Air at approximately 15 l/h is passed through the reaction mixture for 8 hours at said temperature. Cyclooctanol is obtained at a selectivity of 15% and cyclooctanone at a selectivity of 43%, at a cyclooctane conversion rate of 51%.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06852893B2uspto-grants-2005_02