반응 #51727

반응 방정식

3-bromofuran

4-methyl-1-penten-3-ol

sodium bicarbonate

→

title compound

1-Furan-3-yl-4-methyl-pentan-3-one

용매

DMF

반응 조건

후처리

1. 1
   기타The title compound was prepared
2. 2
   기타chromatographed
3. 3
   세척eluting with EtOAc:hexane (5:95 to 10:90)

실험 절차

The title compound was prepared according to General Method 4a using 3-bromofuran (17 mmol), 4-methyl-1-penten-3-ol (25.5 mmol), tetrabutyl ammonium chloride (17 mmol), sodium bicarbonate (42.5 mmol), DMF (15 mL), and palladium acetate (0.9 mmol). The title compound was flash chromatographed eluting with EtOAc:hexane (5:95 to 10:90).

출처