반응 #514154

ord-11312da6a2834eb4a44313c189813ae9

반응 방정식

OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-mannitol
OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol
→
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-glucose

반응물

OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-mannitol
OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도is heated for 30 minutes to 80° C. with 67.5 g (227 mmole) of BEPDIB
  2. 2
    workup.DISTILLATIONAfter the readily volatile constituents have been distilled off in vacuo (10-3Torr), 11.6 g (96%) of bp. 108° C./10-3Torr and [α]D20 9.7 (c=6, CCl4) and 9.2 g (91%) of viscous residue
  3. 3
    기타are obtained

실험 절차

A mixture of 7.46 g (41 mmole) of D-mannitol and 6.2 g (41 mmole) of xylitol is heated for 30 minutes to 80° C. with 67.5 g (227 mmole) of BEPDIB. After the readily volatile constituents have been distilled off in vacuo (10-3Torr), 11.6 g (96%) of bp. 108° C./10-3Torr and [α]D20 9.7 (c=6, CCl4) and 9.2 g (91%) of viscous residue are obtained.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04172195uspto-grants-1979_10