반응 #51334

ord-5197e12bfb334a10b3329c8112e9cee0

반응 방정식

Nc1ccc2ccccc2c1
2-aminonaphthalene
CCOC(=O)C(C)=O
ethyl pyruvate
CCOC(=O)[C@H](C)Nc1ccc2ccccc2c1
title compound
CCOC(=O)[C@H](C)Nc1ccc2ccccc2c1
N-(2-naphthyl)alanine ethyl ester

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타Purification

실험 절차

Following reductive amination General Procedure AA above and using 2-aminonaphthalene (Aldrich) and ethyl pyruvate (Aldrich), the title compound was prepared as a solid having a melting point of 52-56° C. The reaction was monitored by silica gel tlc (Rf=0.50 in 25% EtOAc/hexanes). Purification was by flash chromatography with silica gel using 25% EtOAc/hexanes as the eluant.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06849650B2uspto-grants-2005_02