반응 #50434

반응 방정식

6-[(2-chloro-α,α,α,6-tetrafluoro-p-tolyl)oxy]-α-methyl-1H-benzotriazole-1-acetaldehyde oxime

→

title compound ( I )

6-[(2-chloro-α,α,α,6-tetrafluoro-p-tolyl)oxy]-α-methyl-1H-benzotriazole-1-acetonitrile

용매

acetic anhydride

반응 조건

후처리

1. 1
   농축concentrated in vacuo
2. 2
   기타to give an oil residue
3. 3
   기타The residue is chromatographed on silica gel

실험 절차

A solution of 6-[(2-chloro-α,α,α,6-tetrafluoro-p-tolyl)oxy]-α-methyl-1H-benzotriazole-1-acetaldehyde oxime (5.0 g, 0.012 mol) in acetic anhydride is allowed to stand at 22° C. for 20 hours and concentrated in vacuo to give an oil residue. The residue is chromatographed on silica gel using chloroform as eluant to afford the title compound (I), 2.0 g, mp 118°-119° C., identified by elemental and NMR analyses and the title compound (II), 2.1 g, mp 95°-97° C., identified by elemental and NMR analyses.

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